Product ID:01963 TMGL PREMIUM
MSDS Date:05/02/1996
FSC:9150
NIIN:00N009009
MSDS Number: CFLMP

TEXACO

HOUSTON, TX 77210-4427
US

Emergency Phone: 914-831-3400;800-424-9300(CHEMTREC)

Info Phone: 914-838-7104

Cage: 06668

TEXAS INSTRUMENTS INC INFORMATION TECHNOLOGY GROUP

1444 HOUSTON, TX 77251 US

Telephone: 800-336-5236

Cage: 06668

TO CAUSE SKIN CANCER WHEN RPTDLY APPLIED TO MOUSE

RTECS: 9999999ZZ

THE IARC HAS CONCLUDED THAT ASPHALTS DISSOLVED IN

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QUALIFIED MED PERS MAY ADMIN OXYG. GET MED

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ASPHALT OCCURS, DO NOT USE SOLVS(GASOLINE, KEROSENE,

RTECS: 9999999ZZ

EMULSIFYING AGENT POLYOXYETHYLENE SORBITAN (TWEEN

RTECS: 9999999ZZ

OPHTHALMIC FORMULATIONS CONTAINING POLYSORBATE CAN

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CONJUNCTIVA. FOR MORE INFORMATION CONTACT NEHC .

RTECS: 9999999ZZ

FOR THE PETROLEUM EXEMPTION (CERCLA) SECTION

RTECS: 9999999ZZ

DISP, WHETHER PROD MEETS RCRA CRITERIA FOR

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MIXTURES, PROCESSES, ETC MAY RENDER THE RESULTING

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OF CONTAMINANT. NIOSH APPRVD AIR SUPPLIED RESPS

RTECS: 9999999ZZ

CONTAMINENT OR OXYGEN CONTENT IS UNKNOWN.

RTECS: 9999999ZZ

ASPHALT

CAS: 8052-42-4

RTECS: CI9900000

Fraction By Weight: 80-94.9%

OSHA PEL N/K

ACGIH TLV: 5 MG/M3; (FUME)

MINERAL OIL

CAS: 72623-83-7

Fraction By Weight: 3-9.99%

OSHA PEL N/K

ACGIH TLV: N/K

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPYL ALCOHOL (SARA 313)

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM/500 STEL

MATL FROM HIGH PRESS EQUIP, PINHOLE LEAKS/HIGH PRESS

RTECS: 9999999ZZ

TREATED, CAN CAUSE SEV INJURY, INCL DISFIGUREMENT,

RTECS: 9999999ZZ

TO PVNT SUCH SERIOUS INJURY, IMMED MED ATTN SHOULD BE

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WHEN OVERHEATED, PROD MAY RELASE HYDROGEN

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IRRIT OF EYES & RESP TRACT, HDCH, DIZZ, NAUS, VOMIT,

RTECS: 9999999ZZ

CONDENSED

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) >8.00 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES:MAY CAUSE MINIMAL IRRIT,
EXPERIENCED AS TEMPORARY DISCOMFORT. SKIN:BRIEF CONT IS NOT
IRRITATING. PRLNGD CONT, AS W/CLTHG WETTED W/MATL, MAY CAUSE DEFAT
OF SKIN/IRIT, SEEN AS LOC REDNESS W/ POSS MILD DISCOMFORT. OTHER
THAN POTNTLSKIN IRRIT, EFTS NOTED, ACUTE ADVERSE EFTS ARE NOT
EXPECTED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: FROM BRIEF SKIN CONT.
INHAL:VAPS/MIST, ESPECIALLY AS GENERATED FROM HEATING MATL/FROM
EXPOS IN POORLY VENTILATED AREAS/CONFINED SPACES, MAY BE IRRITATING
& CAUSE DISCOMFORT IN NOSE & THROAT, NASAL DISCHARGE, & COUGH.
PRLNGD OVEREXP MAY CAUSE DFCLTY BRTHG. INGEST:IF MORE THAN SEVERAL
MOUTHFULS ARE (SUPDAT)
Medical Cond Aggravated by Exposure:BECAUSE OF ITS DEFATTING
PROPERTIES, PROLONGED & REPEATED SKIN CONT MAY AGGRAVATE AN
EXISTING DERMATITIS (SKIN CONDITION).

First Aid:EYES:FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS. GET MED ATTN
IF IRRIT PERSISTS. SKIN:WASH W/PLENTY OF SOAP & WATER FOR SEVERAL
MINS. GET MED ATTN IF IRRIT DEVELOPS/PERSISTS. INGEST:IF MORE THAN
SEVERA L MOUTHFULS OF THIS MATL ARE SWALLOWED,GIVE 2 GLASSES OF
WATER(16 OZ). GET MED ATTN. INHAL:REMOVE TO FRESH AIR. IF NOT
BRTHG, CLEAR PERSON'S AIRWAY & GIVE ARTF RESP. IF BRTHG IS DFCLT,
(ING 14)

Flash Point Method:COC
Flash Point:>300F,>149C
Extinguishing Media:USE WATER SPRAY, DRY CHEM, FOAM/CO*2 TO EXTING
FLAMES.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER
OR FOAM MAY CAUSE FROTHING.
Unusual Fire/Explosion Hazard:HYDROGEN SULFIDE (H*2S) MAY BE RELEASED
IF OVERHEATED.

Spill Release Procedures:CONTAIN SPILL IF POSS, CONTAIN W/ABSORB MATLS
SUCH AS CLAY/SOIL, & SHOVEL UP. AVOID SKIN & EYE CONT. IF
>2,398,081 POUNDS OF PRODUCT IS SPILLED, THEN REPORT SPILL
ACCORDING TO SARA 304 &/OR CERCLA 102 (A) REQUIREMENTS, UNLESS PROD
QUALIFIES(ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CAUTION:CONTAINS/MAY RELEASE HYDROGEN,
SULFIDE GAS WHEN HEATED MAY CAUSE RESP TRACT IRRIT. MIN FEASIBLE
HANDLING TEMPERATURES SHOULD BE MAINTAINED.
Other Precautions:PERIODS OF EXPOSURE TO HIGH TEMPS SHOULD BE
MINIMIZED. WATER CONTAMINATION SHOULD BE AVOIDED.

Respiratory Protection:AIRBORNE CONCS SHOULD BE KEPT TO LOWEST LEVELS
POSS. IF VAP, MIST/DUST IS GENERATED & OCCUP EXPOS LIMIT OF
PROD/ANY COMPONENT OF PROD, IS EXCEEDED, USE APPROP NIOSH APPRVD
AIR PURIFYING/AIR SUPPLIED R ESP AFTER DETERM AIRBORNE CONC (ING
22)
Ventilation:ADEQUATE TO MEET COMPONENT OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WORKERS SHOULD WASH EXPOSED SKIN SEVERAL TIMES
DAILY W/SOAP & WATER. SOILED CLTHG SHOULD BE LAUNDERED/DRY-CLEANED.
Supplemental Safety and Health
HAZ DECOMP PRODS:SULFUR CONTAINING COMPOUNDS. EFTS OF
OVEREXP:SWALLOWED, ABDOM DISCOMFORT, NAUS, & DIARR MAY OCCUR.
TOLUENE APPEARS ON NAVY LISTING OF OCCUP CHEM REPROD HAZARDS. SEEK
CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ
LIST INFO & SAFE HNDLG & EXPOS INFO . OTHER REMARKS: (ING 6)

Vapor Pres:<0.1
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:<0.1%
Appearance and Odor:BLACK BUTTERY SUBSTANCE, PUNGENT ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:UNDER EXTREME TEMPERATURES OR EXTENDED
STORAGE PERIODS, HYDROGEN SULFIDE (H*2S) GAS MAY ACCUM IN
HEAD-SPACE OF CNTNR.
Hazardous Decomposition Products:TOXIC LEVELS OF CO, CO*2, IRRITATING
ALDEHYDES & KETONES. MAY EVOLVE HYDROGEN SULFIDES, SULFUR OXIDES &
OTHER (SUPDAT)

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE, & LOC REGS . THIS
PROD HAS BEEN EVALUATED FOR RCRA CHARACT & DOES NOT MEET CRITERIA
OF HAZ WASTE IF DISCARDED IN ITS PURCHASED FORM. UNDER RCRA, IT IS
RESPONSIBILI TY OF USER OF PROD TO DETERM AT TIME OF(ING 20)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.